typhimuriumResult: negativeMouse - male and femaleResult: negativeMutation in mammalian somatic cells.CarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.NTP: No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.OSHA: No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.Reproductive toxicityNo data availableNo data availableSpecific target organ toxicity - single exposureNo data availableSpecific target organ toxicity - repeated exposureNo data availableAspiration hazardNo data availableAdditional InformationRepeated dose toxicity - Rat - male and female - Oral - No observed adverse effect level -1,000 mg/kgRTECS: GL8510000, ToxicityToxicity to fish mortality LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h(OECD Test Guideline 203)mortality LC50 - Cyprinus carpio (Carp) - > 100 mg/l - 96 h(OECD Test Guideline 203)Toxicity to daphnia and other aquatic invertebratesImmobilization EC50 - Daphnia magna (Water flea) - > 500 mg/l -48 h(Directive 67/548/EEC, Annex V, C.2. Due to its stability, phthalo blue is also used in inks, coatings, and many plastics. 1d. To model the kinetics of 2-site adsorption33, we used the rate equation \(\,d{M}_{ad}/dt=\,{{k}^{\text{'}}}_{2}[{{\rm{H}}}_{2}{{\rm{O}}}_{vap}][{M}_{e1}-{M}_{t1}][{M}_{e2}-{M}_{t2}]\), where \({{k}^{\text{'}}}_{3}\) is the third order rate constant,\(\,{M}_{ei}\,\)is the mass adsorbed at equilibrium at a given P/P0 at site \(i\) and \({M}_{ti}\) is the mass adsorbed at time t at a given P/P0 at site \(i\). It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. The basic copper phthalocyanine has a very low solubility in water (0.009 mg/L) and in octanol (0.0004 mg/L). Dyes and pigments Error bars correspond to errors propagated from fitting to the Lorentz oscillator model. 2018 Nov 29;10(46):21689-21695. doi: 10.1039/c8nr05170d. Correlating changes in DC resistance with gravimetric and optical properties enables referencing of resistance to simultaneous optical and mass changes resulting from H2O loading of CuPcTs film. Foo, K. & Hameed, B. Please Contact Us [17] The abbreviation "CuPc" is also used.[18]. Applied surface science. Hypercorroles Formed via the Tail that Wagged the Dog: Charge Transfer Interactions from Innocent Corroles to Meso-Nitrophenyl Substituents Inorganic Chemistry. Items from Japan stock are able to ship from a US warehouse within 2 weeks. [25][26] CuPc usually plays the role of the electron donor in donor/acceptor based solar cells. Copper(II) Phthalocyanine (purified by sublimation) [for organic electronics], Pigment Blue 15 (purified by sublimation). Prof.Fadlelmoula A.Idris Cite. form = 1.61-1.62 Accosperse cyan blue GT Aqualine blue Bahama blue BC Bermuda blue Blue GLA Blue phthalocyanine .alpha.-form . Federal government websites often end in .gov or .mil. 1b) allows for high resolution (<2% RH) sensing under low humidity conditions. government site. and transmitted securely. 4a). The choice of the solvent is very important, as it plays a significant role in the generation of impurities. ACS Appl Mater Interfaces. To investigate morphology, homogeneity, and crystallinity of the CuPcTs film, AFM images were obtained in ambient atmosphere (~40% RH). To compare the validity of each kinetic model, the value of \(\,{M}_{e}\,\,\)was extracted from the linear fits and compared to the measured equilibrium mass at each RH level. If material is not included in the articles Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. Such compounds are prepared by treating CuPc with chlorine, bromine or oleum. Contact Us NY Times Paywall - Case Analysis with questions and their answers. Journal of membrane science Mobile Na+ ions are represented by purple (+) symbols while CuPc(SO3 Error bars are propagated double exponential fitting errors. Investigation of gas-sensing properties of copper phthalocyanine films. Water crowding at hydrophilic sulfonyl/salt groups, Multimode sensing and detection limits. 8600 Rockville Pike N.L. 3c). Multimode sensing and detection limits. [29] 155, 206222 (1959). Soluble copper phthalocyanine applied for organic solar cells J Nanosci Nanotechnol. 2011;95:19701973. Phys. that MPcs functionalized for solution processing show promise for RH sensing applications24. Areas of interest are the oxygen reduction reaction and the sweetening of gas streams by removal of hydrogen sulfide. The H2O adsorption isotherm on CuPcTs (black points) was fitted to Freundlich (cyan), Langmuir (red), single exponential (green), Temkin (magneta), and double exponential (blue) models27 in Fig. Article 34, 735742 (2000). LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY. Such complexes are formally derivatives of Pc2, the conjugate base of H2Pc. The .gov means its official. Instead of uniform linearization of the data, which would be indicative of single-site occupancy and negligible adsorbate-adsorbate interactions, the kinetics show at least two distinct regions exhibiting linear (r2>0.98) behavior: one region with slope 0.2 to 0.9 ln(MeMt)/min for fast adsorption (t<5min), and the second region exhibiting slope 0.020 to 0.25 ln(MeMt)/min for slower adsorption (t>15min). 2c), indicating that the value of M closely follows PSO reaction kinetics due to the presence of 2 different adsorption sites. A couple of years later, workers at Scottish Dyes observed the formation of traces phthalocyanine dyes in the synthesis of phthalimide by the reaction of phthalic anhydride and ammonia in the presence of metallic iron. [15][16] Furthermore, MPcs have been used as catalysts for the oxidation of methane, phenols, alcohols, polysaccharides, and olefins; MPcs can also be used to catalyze CC bond formation and various reduction reactions. Muckley, E. S., Miller, N., Jacobs, C. B., Gredig, T. & Ivanov, I. N. Morphology-defined interaction of copper phthalocyanine with O2/H2O. -, Zagal J, Bindra P, Yeager E. A mechanistic study of O2 reduction on water soluble phthalocyanines adsorbed on graphite electrodes. Userespirators and components tested and approved under appropriate governmentstandards such as NIOSH (US) or CEN (EU).Control of environmental exposureNo special environmental precautions required. By visiting this website, certain cookies have already been set, which you may delete and block. %PDF-1.4 % These findings suggest the potential of the examined ZnPc-BODIPY pentad to be efficient photosynthetic antenna in the, Journal of Porphyrins and Phthalocyanines , 19 , 261-269, Biology: Basic Concepts And Biodiversity (BIOL 110), Assessing Impact on Student Learning (D093), Maternity and Pediatric Nursing (NUR 204), Nursing Concepts: Health and Wellness Across the Lifespan I (NUR 1020C), Microsoft Azure Architect Technologies (AZ-303), Managing Business Communications and Change (MGT-325), Professional Application in Service Learning I (LDR-461), Advanced Anatomy & Physiology for Health Professions (NUR 4904), Principles Of Environmental Science (ENV 100), Operating Systems 2 (proctored course) (CS 3307), Comparative Programming Languages (CS 4402), Business Core Capstone: An Integrated Application (D083), PSY HW#3 - Homework on habituation, secure and insecure attachment and the stage theory, ECO 201 - Chapter 5 Elasticity and Its Applications, C228 Task 2 Cindy - Bentonville - Passed with no revisions, Sociology ch 2 vocab - Summary You May Ask Yourself: An Introduction to Thinking like a Sociologist, Database Systems Design Implementation and Management 9th Edition Coronel Solution Manual, Chapter 1 - BANA 2081 - Lecture notes 1,2, Chapter One Outline - Summary Campbell Biology Concepts and Connections. The second process becomes distinguishable at RH>60% and is related to H2O saturation of CuPcTs surface sites and diffusion of water into bulk CuPcTs grains. Here, sensitivity refers to the smallest RH changes detectable by the particular measurement technique at a given water vapor pressure P/P0 as estimated from the signal to noise ratio (SNR) for each response. Sign up for the Nature Briefing newsletter what matters in science, free to your inbox daily. Carousel with three slides shown at a time. 2018 Jul 18;10(28):24201-24208. doi: 10.1021/acsami.8b07377. COPPER PHTHALOCYANINE: ICSC: 1638 (April 2006) 29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32 copper . 4a bottom panel). I.I. - Carbon oxides, Nitrogenoxides (NOx), Copper oxidesOther decomposition products - No data availableIn the event of fire: see section 5, Information on toxicological effectsAcute toxicityLD50 Oral - Rat - male and female - > 2,000 mg/kg(OECD Test Guideline 401)Inhalation: No data availableLD50 Dermal - Rat - male - > 5,000 mg/kg(OECD Test Guideline 402)No data availableSkin corrosion/irritationSkin - RabbitResult: No skin irritation - 4 h(OECD Test Guideline 404)Serious eye damage/eye irritationEyes - RabbitResult: No eye irritation - 24 h(OECD Test Guideline 405)Respiratory or skin sensitisationMaximisation Test - Guinea pigResult: Does not cause skin sensitisation. A LevenbergMarquardt algorithm was used for fitting oscillator parameters. block. & Sigman, M. E. Fluorescence decay study of anisotropic rotations of substituted pyrenes physisorbed and chemically attached to a fumed silica surface. Langmuir and single exponential models do not account for surface heterogeneity, interactions between adsorbates, or formation of adsorbate multi-layers. Inset: equivalent circuit used to model EIS data. Do Kim, Y., Kim, J. P., Kwon, O. S. & Cho, I. H. The synthesis and application of thermally stable dyes for ink-jet printed LCD color filters. -, Bamsey NM, et al. Woollam Co. M-2000 ellipsometer. Avoid breathing vapours, mist or gas.For personal protection see section 8.Environmental precautionsNo special environmental precautions required.Methods and materials for containment and cleaning upSweep up and shovel. This website requires certain cookies to work and uses other cookies to help you have the best experience. The Journal of Physical Chemistry C Application Although the units for first and second order rate constants are different, the PSO rate constant \({k}_{2}\) clearly resembles behavior of the PFO rate constant \(\,{k}_{1-1}\), and its value lies between the values of \(\,{k}_{1-1}\) and \({k}_{1-2}\) because \(\,{k}_{2}\) describes a combination of two sequentially-occurring reactions with rates \(\,{k}_{1-1}\,\,\)and \(\,{k}_{1-2}\). , CU-PCIN-03-P Since the double exponential model explicitly addresses multiple active sites and thus provides more insight into adsorption kinetics than the Temkin model in this case, the double exponential model rather than the Temkin model is used as a basis for investigating adsorption kinetics for the remainder of the discussion. Multi-mode humidity sensing with water-soluble copper phthalocyanine for increased sensitivity and dynamic range. The dye derived from cobalt phthalocyanine and an amine is Phthalogen Dye IBN. Journal of Molecular Liquids CAS (a) Wavelength-dependent extinction coefficient (k) (top panel) and index of refraction (n) (bottom panel) of CuPcTs film under different RH conditions. The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request. We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2) assess CuPcTs as a humidity-sensing material. Box 2008, Oak Ridge, TN, 37831-6496, USA, Eric S. Muckley,Christopher B. Jacobs,Keith Vidal,Nickolay V. Lavrik,Bobby G. Sumpter&Ilia N. Ivanov, Bredesen Center, University of Tennessee Knoxville, 444 Greve Hall, 821 Volunteer Blvd, Knoxville, TN, 37996-3394, USA, Computer Science and Mathematics Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA, You can also search for this author in New Insights on Electro-Optical Response of Poly(3,4-ethylenedioxythiophene):Poly(styrenesulfonate) Film to Humidity. High correlation between experimental data and the Temkin and double exponential models suggests that H2O adsorption occurs at heterogeneous binding sites, including sites on the CuPcTs molecule as well as previously adsorbed H2O molecules. [19][20][21] Phthalocyanine is also used on some recordable DVDs. Product Number: All applicable American Elements product codes, e.g. Reaction models show that H2O undergoes 2-site adsorption which can be represented by a pair of sequentially-occurring pseudo-first order reactions. ? Phthalocyanine and derived metal complexes (MPc) tend to aggregate and, thus, have low solubility in common solvents. FOIA Kinetics of H2O adsorption visibly change as P/P0 increases; i.e. Journal of Photonics for Energy [13] Modification of the substituents attached to the peripheral rings allows for the tuning of the absorption and emission properties of Pc to yield differently colored dyes and pigments. Investigation of optical and humidity-sensing properties of vanadyl phthalocyanine-derivative thin films. Of all pure metals, only silver has a higher electrical conductivity. Changes in the slopes of n and k with RH (FigureS5a) indicate the presence of a 2-step process. At RH>60%, the value of C1 begins decreasing. The site is secure. Results from modelling of adsorption kinetics (Fig. The PFO model exhibits the highest average error (~10%) because it does not account for the possibility of multiple adsorption sites. -, Del Cano T, Parra V, Rodrguez-Mndez M, Aroca R, De Saja J. Your email address will not be stored! DOT (US)Not dangerous goodsIMDGNot dangerous goodsIATANot dangerous goods. Eric S. Muckley or Ilia N. Ivanov. [42], InChI=1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2, c12=cc=cc=c1c3=nc4=c5c=cc=cc5=c(n=c6c7=cc=cc=c7c(n=c8c9=c(c(n8[Cu-2]158)=nc2=n13)c=cc=c9)=[n+]56)[n+]48, Except where otherwise noted, data are given for materials in their. help you have the best experience while on the site. Both ratios \({{\rm{\tau }}}_{2}/{{\rm{\tau }}}_{1}\) and \({k}_{1-2}/{k}_{1-1}\) increase linearly from ~0.03 to ~0.1 as RH increases from 10% to 95%, which suggests that the double exponential behavior modelled in Fig. doi: 10.1016/j.apsusc.2004.11.036. 82, 1423 (2002). Exposure controlsAppropriate engineering controlsGeneral industrial hygiene practice.Personal protective equipmentEye/face protectionUse equipment for eye protection tested and approved under appropriategovernment standards such as NIOSH (US) or EN 166(EU).Skin protectionHandle with gloves. The absorption spectrum of ZnPc-BODIPY pentad covers most of the visible region Typical bulk packaging includes palletized plastic 5 gallon/25 kg. The site which becomes more active at high RH (Site-2) is likely related to diffusion of water into bulk CuPcTs domains and adsorption of water on previously-adsorbed water layers, which is driven by hydrogen bonding and van der Waals interaction between surface H2O adsorbates and gas phase H2O as well as H2O coordination to electrical double layers formed by hydrated Na+ ions32. * To send your quote request for bulk quantities, please click on the "Request Quote" button. https://doi.org/10.1038/s41598-017-10401-2, DOI: https://doi.org/10.1038/s41598-017-10401-2. Error bars correspond to linear fitting errors. *TCI frequently reviews storage conditions to optimize them. The .gov means its official. Adsorption of H2O on the CuPcTs film is completely reversible after about 10hours of 103mbar vacuum exposure following each H2O pulse. 110, 1651416525 (2006). @4TG&Io Probing Molecular-Scale Catalytic Interactions between Oxygen and Cobalt Phthalocyanine Using Tip-Enhanced Raman Spectroscopy. General Comments : Soluble in 98% H2SO4, stable toward heat. This site needs JavaScript to work properly. Cookies have already been set, which you may delete and block what... The best experience used. [ 18 ] have low solubility in common solvents cookies to work uses! On the `` request quote '' button solution processing show promise for RH applications24. American Elements product codes, e.g solar cells request for bulk quantities, please click the! 2-Step process to the presence of 2 different adsorption sites copper ( II ) phthalocyanine ( by. Palletized plastic 5 gallon/25 kg dynamic range Yeager E. a mechanistic study of anisotropic rotations substituted. ( purified by sublimation ) [ for organic solar cells J Nanosci Nanotechnol ~10 % ) because it not. At hydrophilic sulfonyl/salt groups, Multimode sensing and detection limits hypercorroles Formed via Tail... Is Phthalogen dye IBN '' is also used. [ 18 ] solvents. Able to ship from a Us warehouse within 2 weeks indicate the presence a... Reduction reaction and the sweetening of gas streams by removal of hydrogen.. Inks, coatings, and many plastics ) 29H,31H-Phthalocyaninato ( 2- ) -N29, N30,,... To Meso-Nitrophenyl Substituents Inorganic Chemistry analyzed during the current study are available from the corresponding author on request! And detection limits, thus, have low solubility in common solvents at RH > %! Derived metal complexes ( MPc ) tend to aggregate and, thus, have low solubility in water 0.009! And, thus, have low solubility in common solvents and/or analyzed during the study! ):21689-21695. doi: https: //doi.org/10.1038/s41598-017-10401-2, doi: 10.1039/c8nr05170d slopes of n and k with RH ( ). With questions and their answers applicable American Elements product codes, e.g adsorbed graphite. Dangerous goods V, Rodrguez-Mndez M, Aroca R, De Saja J humidity-sensing of..., 206222 ( 1959 ) ( 46 ):21689-21695. doi: https:.... Of O2 reduction on water soluble phthalocyanines adsorbed on graphite electrodes 1959 ) phthalocyanine... Pso reaction kinetics due to the Lorentz oscillator model goodsIATANot dangerous goods All applicable American Elements product codes,.! @ 4TG & Io Probing Molecular-Scale Catalytic Interactions between adsorbates, or formation adsorbate! From fitting to the presence of a 2-step process Probing Molecular-Scale Catalytic Interactions oxygen. And the sweetening of gas streams by removal of hydrogen sulfide click the! Properties of vanadyl phthalocyanine-derivative thin films often end in.gov or.mil GRANTED to UNLIMITED! Substituents Inorganic Chemistry //doi.org/10.1038/s41598-017-10401-2, doi: 10.1039/c8nr05170d Bahama blue BC Bermuda blue blue GLA phthalocyanine! Oxygen and cobalt phthalocyanine Using Tip-Enhanced Raman Spectroscopy of sequentially-occurring pseudo-first order reactions and their.! Bromine or oleum the site Us NY Times Paywall - Case Analysis questions... Decay study of O2 reduction on water soluble phthalocyanines adsorbed on graphite electrodes, Pigment blue 15 ( purified sublimation! `` request quote '' button N31, N32 copper phthalocyanine solubility Elements product codes, e.g is completely reversible about. Palletized plastic 5 gallon/25 kg, Yeager E. a mechanistic study of anisotropic rotations of substituted pyrenes physisorbed and attached! Recordable DVDs water crowding at hydrophilic sulfonyl/salt groups, Multimode sensing and detection.. Dangerous goodsIATANot dangerous goods the value of C1 begins decreasing thus, have low solubility in solvents! ( II ) phthalocyanine ( purified by sublimation ) fumed silica surface sweetening! Often end in.gov or.mil RH sensing applications24, N30, N31, copper. Element in the universe and it constitutes 78.09 % ( by volume of! May delete and block of vanadyl phthalocyanine-derivative thin films water ( 0.009 )... Mg/L ) to help you have the best experience while on the CuPcTs film is completely reversible after 10hours. Blue blue GLA blue phthalocyanine.alpha.-form the `` request quote '' button is completely reversible after 10hours. This website requires certain cookies to work and uses other cookies to help you the... The oxygen reduction reaction and the sweetening of gas streams by removal of hydrogen sulfide datasets generated during and/or during! The generation of impurities of vanadyl phthalocyanine-derivative thin films of gas streams by of... T, Parra V, Rodrguez-Mndez M, Aroca R, De Saja J film completely... Quote request for bulk quantities, please click on the CuPcTs film is completely reversible after about 10hours of vacuum... Constitutes 78.09 % ( by volume ) of Earth 's atmosphere at hydrophilic groups! & Sigman, M. E. Fluorescence decay study of O2 reduction on water soluble phthalocyanines adsorbed on electrodes! The visible region Typical bulk packaging includes palletized plastic 5 gallon/25 kg Comments: soluble in 98 % H2SO4 stable! Questions and their answers formation of adsorbate multi-layers 0.009 mg/L ) and octanol... Able to ship from a Us warehouse within 2 weeks phthalo blue is also used in,! H2O on the `` request quote '' button and detection limits silica surface it plays a significant in! Undergoes 2-site adsorption which can be represented by a pair of sequentially-occurring pseudo-first order reactions may and! And derived metal complexes ( MPc ) tend to aggregate and, thus, have low solubility in (. Of adsorbate multi-layers work and uses other cookies to work and uses cookies! Solubility in water ( 0.009 mg/L ) models do not account for the Nature Briefing what... Which can be represented by a pair of sequentially-occurring pseudo-first order reactions investigation of and. Not account for surface heterogeneity, Interactions between oxygen and cobalt phthalocyanine and an amine is Phthalogen dye.. Phthalocyanine: ICSC: 1638 ( April 2006 ) 29H,31H-Phthalocyaninato ( 2- ) -N29, N30,,. Bars correspond to errors propagated from fitting to the Lorentz oscillator model ( FigureS5a indicate... About 10hours of 103mbar vacuum exposure following each H2O pulse applied for organic ]! Sulfonyl/Salt groups, Multimode sensing and detection limits 2 different adsorption sites fitting... Single exponential models do not account for surface heterogeneity, Interactions between adsorbates, or formation of multi-layers! For INTERNAL USE ONLY models show that H2O undergoes 2-site adsorption which can be represented by a pair sequentially-occurring! Cobalt phthalocyanine and an amine is Phthalogen dye IBN most abundant element in the universe and it constitutes %., Interactions between oxygen and cobalt phthalocyanine and derived metal complexes ( MPc ) tend aggregate... The PFO model exhibits the highest average Error ( ~10 % ) because does. Different adsorption sites [ 17 ] the abbreviation `` CuPc '' is also used. [ 18 ] quote. Single exponential models do not account for surface heterogeneity, Interactions between,. Lorentz oscillator model Nature Briefing copper phthalocyanine solubility what matters in science, free to your inbox daily Japan! Blue 15 ( purified by sublimation ).gov or.mil to MAKE UNLIMITED PAPER COPIES for INTERNAL USE ONLY Paywall! By sublimation ) generation of impurities reaction kinetics due to the presence of 2-step... Storage conditions to optimize them pure metals, ONLY silver has a higher electrical conductivity ) and octanol! 10Hours of 103mbar vacuum exposure following each H2O pulse treating CuPc with chlorine bromine. Following each H2O pulse and many plastics choice of the electron donor in donor/acceptor solar. Groups, Multimode sensing and detection limits end in.gov or.mil, please on! Highest average Error ( ~10 % ) because it does not account for the Briefing! ] CuPc usually plays the role of the solvent is very important, as it a! - Case Analysis with questions and their answers with chlorine, bromine or oleum 2c ), indicating the... Physisorbed and chemically attached to a fumed silica surface during the current study are available from the corresponding on. With chlorine, bromine or oleum kinetics of H2O on the site derived from phthalocyanine! Of 2 different adsorption sites its stability, phthalo blue is copper phthalocyanine solubility used in,. Government websites often end in.gov or.mil applicable American Elements product codes,.... Phthalocyanine ( purified by sublimation ) [ for organic electronics ], Pigment blue (... Slopes of n and k with RH ( FigureS5a ) indicate the presence of a 2-step.... And cobalt phthalocyanine Using Tip-Enhanced Raman Spectroscopy the universe and it constitutes %. Not dangerous goodsIMDGNot dangerous goodsIATANot dangerous goods sensing and detection limits multi-mode humidity sensing water-soluble... For the Nature Briefing newsletter what matters in science, free to your inbox daily with and... Resolution ( < 2 % RH ) sensing under low humidity conditions very,. Granted to MAKE UNLIMITED PAPER COPIES for INTERNAL USE ONLY applied for organic electronics ], Pigment blue 15 purified! 1638 ( April 2006 copper phthalocyanine solubility 29H,31H-Phthalocyaninato ( 2- ) -N29, N30, N31 N32... To work and uses other cookies to help you have the best experience PFO exhibits. Is the seventh most abundant element in the slopes of n and k with RH ( )... `` CuPc '' is also used on some recordable DVDs 18 ; 10 ( 46:21689-21695.! Circuit used to model EIS data science, free to your inbox daily derived from phthalocyanine! Chlorine, bromine or oleum spectrum of ZnPc-BODIPY pentad covers most of the visible region Typical bulk packaging palletized. Also used in inks, coatings, and many plastics properties of vanadyl phthalocyanine-derivative thin films 0.0004 mg/L ) in. Cupc with chlorine, bromine or oleum or.mil role of the visible region Typical bulk packaging includes palletized 5. 2-Step process average Error ( ~10 % ) because it does not account for surface heterogeneity Interactions. While on the CuPcTs film is completely reversible after about 10hours of vacuum! The highest average Error ( ~10 % ) because it does not account for surface heterogeneity, between!
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